This volume collects Girl in Gold Boots, Space Mutiny, Hamlet, and Overdrawn at the Memory Bank. Mmmm, cheesy. While not all some of my favourite movies available on DVD (Aside from Gold Boots though, this is a great set), my first MST3K DVDs were chosen merely for price. Not like there's a story you're trying to get in order here. ;)
Although I'd still love to see chronological sets of the entire run, just for posterity, and to have 'em all. Chronological, simply because I find that the easiest way to keep track of them all. I highly doubt the rights issues will ever be worked out for that, though.